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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
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Structural evolution of self-assembled alkanephosphate monolayers on TiO2

Hong-Bo Liu1, Nagaiyanallur V Venkataraman, Nicholas D Spencer

  • 1State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China.

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
|September 23, 2008
PubMed
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No abstract available in PubMed .

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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.