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Updated: Jun 30, 2026

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
Published on: May 29, 2018
Thermal stability and structural characterization of organic/inorganic hybrid nonlinear optical material containing a
Po-Hsun Chang1, Hsieh-Chih Tsai, Yu-Ren Chen
1Department of Chemical Engineering, National Tsing Hua University, Hsinchu, 300 Taiwan, ROC.
Abstract:
In this study, two nonlinear optic hybrid materials with different dimensional alkoxysilane dyes were prepared and characterized. One NLO silane (Cz2PhSO 2OH- TES), a two-dimensional structure based on carbazole, had a larger rotational volume than the other (DR19-TES). Second harmonic ( d 33) analysis verified there is an optimum heating process for the best poling efficiency. The maximum d 33 value of NLO hybrid film containing Cz2PhSO 2OH was obtained for 10.7 pm/V after precuring at 150 degrees C for 3 h and poling at 210 degrees C for 60 min. The solid-state (29)Si NMR spectrum shows that the main factor influencing poling efficiency and thermal stability was cross-linking degree of NLO silane, but not that of TMOS. In particular, the two-dimensional sol-gel system has a greater dynamic and temporary stability than the one-dimensional system due to Cz2PhSO 2OH-TES requiring a larger volume to rotate in the hybrid matrix after cross-linking.
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