Related Experiment Video
Updated: Jun 29, 2026

Cooling Rate Dependent Ellipsometry Measurements to Determine the Dynamics of Thin Glassy Films
Published on: January 26, 2016
Quantitative theory of a relaxation function in a glass-forming system
Edan Lerner1, Itamar Procaccia
1Department of Chemical Physics, The Weizmann Institute of Science, Rehovot 76100, Israel.
Abstract:
We present a quantitative theory for a relaxation function in a simple glass-forming model (binary mixture of particles with different interaction parameters). It is shown that the slowing down is caused by the competition between locally favored regions (clusters) that are long-lived but each of which relaxes as a simple function of time. Without the clusters, the relaxation of the background is simply determined by one typical length, which we deduce from an elementary statistical mechanical argument. The total relaxation function (which depends on time in a nontrivial manner) is quantitatively determined as a weighted sum over the clusters and the background. The "fragility" in this system can be understood quantitatively since it is determined by the temperature dependence of the number fractions of the locally favored regions.
Related Concept Videos
Entropy
Atomic Nuclei: Types of Nuclear Relaxation
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers energy to a nearby...
Reaction Quotient
Clausius-Clapeyron Equation
Glassware Calibration
Volumetric flasks: Volumetric flasks are designed to prepare aqueous solutions of precise volumes accurately with a calibration line on the neck. To calibrate a volumetric flask, it is important to fill it with distilled...
Calculation of First-Law Quantities II

