Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Controlled-Potential Coulometry: Electrolytic Methods01:17

Controlled-Potential Coulometry: Electrolytic Methods

Controlled-potential coulometry, also known as potentiostatic coulometry, employs a three-electrode system in which the working electrode's potential is precisely regulated using a potentiostat. Platinum working electrodes are utilized for positive potentials, while mercury pool electrodes are favored for extremely negative potentials. The platinum counter electrode is separated from the analyte using a membrane or salt bridge to avoid interference in the analysis.
The chosen potential ensures...
Ion-Exchange Chromatography01:09

Ion-Exchange Chromatography

Ion-exchange chromatography, or IEC, is a technique for separating ions based on their affinity for the stationary phase. The stationary phase is a cross-linked polymer resin with covalently attached ionic functional groups. The functional groups can be either positively charged (cation exchangers) or negatively charged (anion exchangers). A cation exchanger consists of a polymeric anion and active cations, while an anion exchanger is a polymeric cation with active anions. The choice of...
Electrodeposition01:08

Electrodeposition

Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Controlled-Current Coulometry: Overview01:27

Controlled-Current Coulometry: Overview

Controlled current coulometry, also known as amperostatic coulometry, is a technique used in electrochemical analysis to measure the quantity of a substance through the controlled passage of current. It involves the application of a constant current to an electrochemical cell containing the analyte of interest. As the current flows through the cell, the analyte undergoes a redox reaction at the electrode surface, resulting in a charge transfer. By monitoring the time required for a certain...
Ion Exchange01:17

Ion Exchange

Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or basic...
Potentiometry: Membrane Electrodes01:15

Potentiometry: Membrane Electrodes

Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at the...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Massive degeneration and atrophy of the native heart after heterotopic transplantation: a case report.

Transplantation proceedings·2009
Same author

Determination of transition metals in human hair by high-performance liquid chromatography using sodium hexadecane-sulfonate coated columns.

Talanta·2008
Same author

Sequential injection system for the spectrophotometric determination of reducing sugars in wines.

Talanta·2008
Same author

Potentiometric determination of urea by sequential injection using Jack bean meal crude extract as a source of urease.

Talanta·2008
Same author

Construction and evaluation of ion selective electrodes for nitrate with a summing operational amplifier. Application to tobacco analysis.

Talanta·2008
Same author

An improved leaping detector for flow analysis applied to iron speciation in drugs.

Journal of automated methods & management in chemistry·2008
Same journal

Automated colorimetric determination of recombinant fungal laccase activity in fermentation sarples using syringaldazine as chromogenic substrate.

The Journal of automatic chemistry·2008
Same journal

Diagnosis of infections in newborns using a new particle-mediated immunoassay for serum C-reactive protein.

The Journal of automatic chemistry·2008
Same journal

Automation photometer of Hitachi U-2000 spectrophotometer with RS-232C-based computer.

The Journal of automatic chemistry·2008
Same journal

An automated system for the measurement of hydrogen peroxide in industrial applications.

The Journal of automatic chemistry·2008
Same journal

Simultaneous spectrophotometric determination of manganese, zinc and cobalt by kernel partial least-squares method.

The Journal of automatic chemistry·2008
Same journal

The automatic methods group newsletter.

The Journal of automatic chemistry·2008
See all related articles

Related Experiment Video

Updated: Jun 28, 2026

Precise Electrochemical Sizing of Individual Electro-Inactive Particles
05:03

Precise Electrochemical Sizing of Individual Electro-Inactive Particles

Published on: August 4, 2023

Computer-controlled ion-selective electrode switch.

R A Lapa1, J L Lima

  • 1Physical Chemistry Department Faculty of Pharmacy University of Porto Porto 4000 Portugal.

The Journal of Automatic Chemistry
|January 1, 1991
PubMed
Summary
This summary is machine-generated.

A new microcomputer-controlled electrode switch enables automated sequential determinations using multiple ion-selective electrodes in laboratory settings. This device enhances analytical efficiency and expands the capabilities of existing potentiometric equipment.

More Related Videos

Electrochemical Etching and Characterization of Sharp Field Emission Points for Electron Impact Ionization
06:58

Electrochemical Etching and Characterization of Sharp Field Emission Points for Electron Impact Ionization

Published on: July 12, 2016

Fabrication of a Solution-gated Indium-Tin-Oxide-based One-piece Transistor Enabling Sensitive Biosensing
10:45

Fabrication of a Solution-gated Indium-Tin-Oxide-based One-piece Transistor Enabling Sensitive Biosensing

Published on: August 29, 2025

Related Experiment Videos

Last Updated: Jun 28, 2026

Precise Electrochemical Sizing of Individual Electro-Inactive Particles
05:03

Precise Electrochemical Sizing of Individual Electro-Inactive Particles

Published on: August 4, 2023

Electrochemical Etching and Characterization of Sharp Field Emission Points for Electron Impact Ionization
06:58

Electrochemical Etching and Characterization of Sharp Field Emission Points for Electron Impact Ionization

Published on: July 12, 2016

Fabrication of a Solution-gated Indium-Tin-Oxide-based One-piece Transistor Enabling Sensitive Biosensing
10:45

Fabrication of a Solution-gated Indium-Tin-Oxide-based One-piece Transistor Enabling Sensitive Biosensing

Published on: August 29, 2025

Area of Science:

  • Analytical Chemistry
  • Electrochemistry
  • Instrumentation

Background:

  • Potentiometric determinations often require manual electrode switching, limiting efficiency.
  • Automating sequential measurements with multiple ion-selective electrodes (ISEs) is challenging.
  • Integration with existing laboratory analytical equipment is desirable.

Purpose of the Study:

  • To describe the construction of a microcomputer-controlled electrode switch.
  • To enable automated sequential determinations using multiple ISEs.
  • To assess the analytical performance and behavior of the developed switch.

Main Methods:

  • Design and construction of a microcomputer-controlled electrode switching system.
  • Coupling the switch to standard laboratory analytical equipment.
  • Sequential potentiometric determinations using various ISEs.

Main Results:

  • Successful construction of a functional microcomputer-controlled electrode switch.
  • Demonstrated compatibility with common analytical instrumentation.
  • Effective performance in sequential determinations with multiple ISEs.

Conclusions:

  • The microcomputer-controlled electrode switch facilitates automated potentiometric analysis.
  • It enhances laboratory efficiency for sequential measurements with ISEs.
  • The device offers a versatile solution for upgrading analytical systems.