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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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Novel low-melting salts with donor-acceptor substituents as targets for second-order nonlinear optical applications

Zhi-Qiang Zhu1, Shaoji Xiang, Qing-Yun Chen

  • 1Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai, 200032, PR China.

Chemical Communications (Cambridge, England)
|October 22, 2008
PubMed

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Treating arylamines with nitrous acid gives aryldiazonium salts that are effective substrates in nucleophilic aromatic substitution reactions. The diazonio group in these salts can be easily displaced by different nucleophiles, yielding a wide variety of substituted benzenes. The leaving group departs as nitrogen gas, and this easy elimination is the driving force for the substitution reaction.
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