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Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Polyborylated reagents for modern organic synthesis.
Masaki Shimizu1, Tamejiro Hiyama
1Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, Japan.
Summary
Advances in diborylation chemistry enable the synthesis of diverse gem- and vic-diborylated compounds. These reagents facilitate novel synthetic methods for polyborylated compounds and multiple bond formation with excellent stereocontrol.
Area of Science:
- Organic Chemistry
- Synthetic Chemistry
- Organoboron Chemistry
Background:
- Diborylated compounds are crucial building blocks in organic synthesis.
- Recent advancements have expanded the accessibility of gem- and vic-diborylated compounds.
- These reagents offer unique reactivity for constructing complex molecules.
Purpose of the Study:
- To review the preparative methods for gem- and vic-diborylated reagents.
- To summarize synthetic reactions utilizing di- and polyborylated compounds.
- To highlight the application of these reagents in multiple bond formation.
Main Methods:
- Gem-diborylation of lithium carbenoids.
- Vic-diborylation of carbon-carbon multiple bonds using diboron compounds.
- Development of novel synthetic methodologies for polyborylated reagents.
Main Results:
- Readily available gem- and vic-diborylated compounds.
- Invention of polyborylated reagents.
- Development of synthetic methods with superior stereocontrol.
- Facilitation of multiple bond formation.
Conclusions:
- Diborylated reagents are versatile tools in modern organic synthesis.
- These compounds enable the construction of complex molecular architectures.
- The review provides a comprehensive overview of their preparation and synthetic utility.
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