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Raman and IR Spectroelectrochemical Methods as Tools to Analyze Conjugated Organic Compounds
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Spectroscopic units in conjugated polymers: a quantum chemically founded concept?

Wichard J D Beenken1, Tõnu Pullerits

  • 1Department of Chemical Physics, Lund University, 22100 Lund, Sweden.

The Journal of Physical Chemistry. B
|October 28, 2008
PubMed
Summary

Spectroscopic units in conjugated polymers form dynamically. Quantum chemistry reveals that excited states in polythiophene localize due to nuclear-electronic interactions, not static defects.

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