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Updated: Jun 28, 2026
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
Published on: March 20, 2017
Stabilities of some cyclopentadienide metal complexes
1Department of Chemistry University of Waterloo Waterloo, Ontario, Canada.
Talanta
|January 1, 1972
Summary
This study investigated metal complexes with cyclopentadienide in different solutions. Stability constants were determined for hydrogen, manganese, iron, cobalt, nickel, and palladium complexes.
Area of Science:
- Coordination Chemistry
- Inorganic Chemistry
Background:
- Cyclopentadienide is a versatile ligand in coordination chemistry.
- Understanding metal complex stability is crucial for various applications.
Purpose of the Study:
- To investigate the composition and stability of metal-cyclopentadienide complexes.
- To determine stability constants in aqueous and dimethylformamide solutions.
Main Methods:
- Spectrophotometric analysis was employed.
- Effective and overall stability constants were calculated.
Main Results:
- The composition and stabilities of various metal-cyclopentadienide complexes were elucidated.
- Stability constants were successfully determined for manganese(II), iron(II), cobalt(II), nickel(II), and palladium(II) complexes.
Conclusions:
- The study provides valuable data on the stability of metal-cyclopentadienide complexes.
- Findings contribute to the understanding of coordination chemistry in different solvent systems.
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