Ion-exchange behaviour of metals on deae-cellulose in methanol-thiocyanate-hydrochloric acid media
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Published on: April 16, 2018
1Laboratory for Analytical Chemistry, Faculty of Engineering, University of Chiba, Yayoi-cho, Chiba, Japan.
Abstract:
Only a few metals can be adsorbed on DEAE-cellulose from aqueous thiocyanate-chloride media. However, several metal ions, including Cu(II), Zn, Cd, In, Bi and U(VI), exhibit enhanced adsorption on DEAE-cellulose from methanol-thiocyanate-hydrochloric acid mixtures. The distribution coefficients for these metals are given as functions of methanol, ammonium thiocyanate and hydrochloric add concentration. Differences in adsorption among metals permit many useful separations, including those of two-, three- and four-component mixtures, on short columns containing 1-1.5 g of DEAE-cellulose.
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