Determination of stability constants for rare earth elements and fulvic acids extracted from different soils

Fulvic acids (FAs) were extracted by alkali extraction from different soil samples in China, then purified using resins and characterized by Fourier transform infrared spectroscopy. The complexing ability of FAs was investigated by measuring the stability constants of rare earth elements (REEs) (La(3+), Ce(3+), Sm(3+), Gd(3+), Y(3+)) with FAs by the ion exchange technique. The results indicated that maximum binding ability forY(3+) (4.41 approximately 4.44) was higher than other REEs (La(3+), Ce(3+), Sm(3+), Gd(3+)) (0.72 approximately 1.03). There were two types of binding sites in the functional groups of fulvic acids. The complexing reaction followed two steps. The stability constants (K(1) and K(2)) of REEs with FAs were calculated from experimental data by division of Scatchard plots into two straight-line segments. Y(3+) (logK(1)=5.72+/-0.05, logK(2)=4.83+/-0.01) also has higher stability constants than the other four REEs (logK(1)=4.37+/-0.16, logK(2)=3.62+/-0.28).