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Updated: Jun 28, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Rotational spectrum and equilibrium structure of silanethione, H2Si=S
Sven Thorwirth1, Jürgen Gauss, Michael C McCarthy
1Max-Planck-Institut für Radioastronomie, Auf dem Hügel 69, Bonn, Germany. sthorwirth@mpifr-bonn.mpg.de
Abstract:
Unsubstituted silanethione, H(2)Si=S, has been characterized experimentally for the first time by means of rotational spectroscopy; the equilibrium structure of this fundamental molecule has been evaluated through a combination of experimental data from a total of ten isotopologues and results of high-level coupled-cluster calculations.
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