Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Woodward–Hoffmann Selection Rules and Microscopic Reversibility01:34

Woodward–Hoffmann Selection Rules and Microscopic Reversibility

Electrocyclic reactions, cycloadditions, and sigmatropic rearrangements are concerted pericyclic reactions that proceed via a cyclic transition state. These reactions are stereospecific and regioselective. The stereochemistry of the products depends on the symmetry characteristics of the interacting orbitals and the reaction conditions. Accordingly, pericyclic reactions are classified as either symmetry-allowed or symmetry-forbidden. Woodward and Hoffmann presented the selection criteria for...
Entropy Change in Reversible Processes01:10

Entropy Change in Reversible Processes

In the Carnot engine, which achieves the maximum efficiency between two reservoirs of fixed temperatures, the total change in entropy is zero. The observation can be generalized by considering any reversible cyclic process consisting of many Carnot cycles. Thus, it can be stated that the total entropy change of any ideal reversible cycle is zero.
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
Ziegler–Natta Chain-Growth Polymerization: Overview01:17

Ziegler–Natta Chain-Growth Polymerization: Overview

Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta catalyst, high molecular...
Carrier Generation and Recombination01:22

Carrier Generation and Recombination

Carrier generation is the process by which electron-hole pairs (EHPs) are created within the semiconductor. In direct-bandgap semiconductors, such as gallium arsenide (GaAs), this occurs efficiently when energy absorption prompts valence electrons to leap into the conduction band, leaving behind holes.
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...
Reversible and Irreversible Processes01:14

Reversible and Irreversible Processes

The thermodynamic processes can be classified into reversible and irreversible processes. The processes that can be restored to their initial state are called reversible processes. It is only possible if the process is in quasi-static equilibrium, i.e., it takes place in infinitesimally small steps, and the system remains at equilibrium However, these are ideal processes and do not occur naturally. An ideal system undergoing a reversible process is always in thermodynamic equilibrium within...
Cationic Chain-Growth Polymerization: Mechanism00:57

Cationic Chain-Growth Polymerization: Mechanism

The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the generated carbocation,...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Early detection of ICU-acquired infections using high-frequency electronic health record data.

BMC medical informatics and decision making·2025
Same author

Criticality is Associated with Future Psychotherapy Response in Patients with Post-Traumatic Stress Disorder-A Pilot Study.

Chronic stress (Thousand Oaks, Calif.)·2025
Same author

Brain-inspired computing with fluidic iontronic nanochannels.

Proceedings of the National Academy of Sciences of the United States of America·2024
Same author

Learning models for classifying Raman spectra of genomic DNA from tumor subtypes.

Scientific reports·2023
Same author

Transport and nonequilibrium phase transitions in polygonal urn models.

Chaos (Woodbury, N.Y.)·2022
Same author

Statistical Classification for Raman Spectra of Tumoral Genomic DNA.

Micromachines·2022

Related Experiment Video

Updated: Jun 28, 2026

Dynamic Light-Induced Protein Patterns at Model Membranes
07:10

Dynamic Light-Induced Protein Patterns at Model Membranes

Published on: February 23, 2024

Competitive nucleation in reversible probabilistic cellular automata.

Emilio N M Cirillo1, Francesca R Nardi, Cristian Spitoni

  • 1Dipartimento Me. Mo. Mat., Università degli Studi di Roma La Sapienza, via A. Scarpa 16, Rome, Italy.

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|November 13, 2008
PubMed
Summary

This study examines competitive nucleation using probabilistic cellular automata, revealing a unique metastable phase dependent on magnetic fields and self-interaction. The findings show behaviors analogous to the stochastic Blume-Capel model.

More Related Videos

Plasmid-derived DNA Strand Displacement Gates for Implementing Chemical Reaction Networks
07:50

Plasmid-derived DNA Strand Displacement Gates for Implementing Chemical Reaction Networks

Published on: November 25, 2015

Structure-Based Simulation and Sampling of Transcription Factor Protein Movements along DNA from Atomic-Scale Stepping to Coarse-Grained Diffusion
09:17

Structure-Based Simulation and Sampling of Transcription Factor Protein Movements along DNA from Atomic-Scale Stepping to Coarse-Grained Diffusion

Published on: March 1, 2022

Related Experiment Videos

Last Updated: Jun 28, 2026

Dynamic Light-Induced Protein Patterns at Model Membranes
07:10

Dynamic Light-Induced Protein Patterns at Model Membranes

Published on: February 23, 2024

Plasmid-derived DNA Strand Displacement Gates for Implementing Chemical Reaction Networks
07:50

Plasmid-derived DNA Strand Displacement Gates for Implementing Chemical Reaction Networks

Published on: November 25, 2015

Structure-Based Simulation and Sampling of Transcription Factor Protein Movements along DNA from Atomic-Scale Stepping to Coarse-Grained Diffusion
09:17

Structure-Based Simulation and Sampling of Transcription Factor Protein Movements along DNA from Atomic-Scale Stepping to Coarse-Grained Diffusion

Published on: March 1, 2022

Area of Science:

  • Statistical Mechanics
  • Computational Physics
  • Dynamical Systems

Background:

  • Competitive nucleation is a critical phenomenon in phase transitions.
  • Probabilistic cellular automata (PCA) offer a framework for modeling complex dynamics.
  • Understanding metastability is key to predicting system behavior.

Purpose of the Study:

  • To investigate competitive nucleation dynamics within PCA.
  • To analyze the influence of self-interaction on metastability.
  • To identify emergent phases and their dependence on system parameters.

Main Methods:

  • Utilizing a dynamical approach to study PCA.
  • Analyzing the interplay between magnetic field and self-interaction.
  • Observing system evolution through configurations.

Main Results:

  • An intermediate metastable phase was identified.
  • This phase consists of two flip-flopping chessboard configurations.
  • The phase emergence is contingent on the ratio of magnetic field to self-interaction.

Conclusions:

  • The study elucidates a novel metastable phase in PCA.
  • The observed behavior parallels that of the stochastic Blume-Capel model with Glauber dynamics.
  • Findings contribute to the understanding of nucleation and phase transitions in complex systems.