Effects of film structure on electrochromic properties of the multilayer films containing polyoxometalates
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Updated: Jun 27, 2026
Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
Bingbing Xu1, Lin Xu, Guanggang Gao
1Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024, PR China.
Abstract:
Multilayer films of tungstophosphate anion (P(2)W(18)) and poly(allylamine hydrochloride) (PAH) were fabricated on quartz and ITO substrates by layer-by-layer self-assembly method. These films were characterized by UV-vis spectroscopy, cyclic voltammetry (CV), chronoamperometric (CA), chronocoulometry (CC) and atomic force microscopy (AFM). The effects of film structure on multilayer electrochromic properties were investigated. The electrochromic responses of the composite films were related to the surface coverage of anion and multilayer thickness. It was found that higher concentration of polycation and anion, or adding salt to the polycation solution used for multilayer film preparation led to thicker and denser film structure which improved optical contrast and coloration efficiency whereas prolonged response time.
