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Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile
Published on: October 30, 2018
Phenyl cinnamate derivatives from Oxalis pes-caprae
Marina Dellagreca1, Raffaella Purcaro, Lucio Previtera
1UDR Napoli 4 (Consorzio INCA), Dipartimento di Chimica Organica e Biochimica, Università Federico II, Complesso Universitario Monte Sant'Angelo, Via Cinthia 4, IT-80126 Napoli. dellagre@unina.it
Abstract:
During the screening of Mediterranean invasive plants, Oxalis pes-caprae was identified as promising species. The fresh leaves and twigs of the plant were crumbled and extracted with AcOEt. The solution was concentrated, and separated into acidic and neutral fractions. The crude neutral residue was fractionated by chromatographic procedures, followed by structure elucidation on the basis of 1H- and 13C-NMR, and MS data analysis, and six new phenyl cinnamate derivatives were identified. The phytotoxic effects of the isolated compounds on the germination and growth of the dicotyledon Lactuca sativa L. (lettuce) were studied in the concentration range from 10(-4) to 10(-7) M.
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