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Controlled synthesis and characterization of the enhanced local field of octahedral Au nanocrystals

Jinhwa Heo1, Deok-Soo Kim, Zee Hwan Kim

  • 1Department of Chemistry, Research Institute of Natural Science, and Environmental Biotechnology National Core Research Center, Gyeongsang National University, 660-701, Jinju, Korea.

Chemical Communications (Cambridge, England)
|December 17, 2008
PubMed

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Crystal Field Theory - Octahedral Complexes02:58

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...