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Updated: Jun 26, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Signature of low-dimensional diffusion in complex systems
N Malikova1, S Longeville, J M Zanotti
1Laboratoire Léon Brillouin, UMR CEA-CNRS 12, CEA Saclay, 91191 Gif-sur-Yvette, France. natalie.malikova@cea.fr
Abstract:
We present a clear signature of the dimensionality of water diffusion in a powder sample of a synthetic hectorite (a model clay), by analyzing the corresponding neutron scattering functions. The data follow the theoretical predictions for a powder-averaged two-dimensional diffusion, with a two-dimensional diffusion coefficient of 0.75 x 10(-9) m2 s(-1). Neutron scattering data of bulk water are used as a reference, representing motion in three dimensions. The approach is based on analyzing the scattered intensity at zero energy transfers, along with the broadening of the scattering functions, collected at a wide range of energy resolutions. The mathematical relationship between these two quantities follows, for a given shape of the resolution function, a universal master curve, independent of the diffusion coefficient, but strongly dependent on the dimensionality of the motion, which can thus be determined with clarity.
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