Dithienylcyclopentenes-containing transition metal bisterpyridine complexes directed toward molecular electronic...

There is continuing interest in the design and synthesis of functional materials for applications in molecular electronics and information storage. Of particular interest are systems that can provide multiple means for controlling transport through well-defined and stable electronic and/or redox states. We report herein the synthesis and characterization of a system containing transition-metal complexes along with dithienylethene (DTE) units so as to achieve photo and redox control of transport. A facile synthetic methodology was developed to assemble and couple metal terpyridine (M-tpy) complexes with the photochromic DTE unit in a linear structure with M-DTE-M or DTE-M-DTE arrangements, with emphasis on the latter series. The photochromic properties of these assemblies were examined by monitoring the changes in their UV/vis spectra upon irradiation at specific wavelengths capable of triggering the open/closed isomerization in the DTE units. Their electrochromic properties were studied via cyclic voltammetry and controlled potential electrolysis experiments. Complexes 10 (PhDTE-Fe-DTEPh) and 11 (PhDTE-Co-DTEPh) with phenyl-ending groups were found to be both photochromic and electrochromic, so they represent excellent candidates for further elaborations. The Fe(II)-containing complex 8 (ClDTE-Fe-DTECl) with chloride-ending groups was photochromically inactive but could undergo the electrochemically induced open-to-closed isomerization. On the contrary, the electrochromically inactive complex 9 (ClDTE-Co-DTECl) underwent cyclization under ultraviolet irradiation.