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A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
Published on: May 9, 2014
Processing and near-field optical properties of self-assembled plasmonic nanoparticle networks
Frédéric Bonell1, Audrey Sanchot, Erik Dujardin
1NanoSciences Group, CEMES/CNRS, UPR 8011, 29 rue Jeanne Marvig, 31055 Toulouse Cedex 4, France.
Abstract:
We report on recent progress in the production and the deposition on surfaces of dielectric materials of self-assembled metallic nanoparticle systems able to organize into branched networks. We emphasize the interest of these new objects for tailoring novel near-field optical properties that could be the basis for optical energy transport in systems of extremely reduced sizes. The experimental optical spectra of such chain networks in solution can be very well reproduced by applying the coupled-dipole approximation scheme. In this paper, we apply this method to investigate the near-field optical properties of self-assembled plasmonic nanoparticle networks deposited on transparent surfaces.

