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Batch adsorption studies for chromium removal.

S Sivamani1, V Prince Immanuel

  • 1Department of Biotechnology, Faculty of Engineering, Technology and Management Studies, Vinayaka Missions University, Periyaseeragapadi, Salem - 636 308, India. dr_sivamani@rediffmail.com

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Nitric acid treated pongamia leaf powder effectively removes hexavalent chromium (Cr (VI)) from water. This study optimized pH, contact time, and concentration for efficient chromium adsorption.

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Area of Science:

  • Environmental Science
  • Water Treatment
  • Adsorption Technology

Background:

  • Hexavalent chromium (Cr (VI)) is a toxic heavy metal pollutant.
  • Industrial wastewater poses a significant risk to aquatic ecosystems and human health.
  • Developing cost-effective adsorbents for Cr (VI) removal is crucial.

Purpose of the Study:

  • To investigate the adsorption of hexavalent chromium (Cr (VI)) using pongamia leaf powder.
  • To evaluate the efficacy of crude pongamia leaf powder (CPLP) and nitric acid treated pongamia leaf powder (APLP) as adsorbents.
  • To determine the optimal conditions for chromium removal.

Main Methods:

  • Crude pongamia leaf powder (CPLP) and nitric acid treated pongamia leaf powder (APLP) were prepared and used as adsorbents.
  • Batch adsorption experiments were conducted to study the effects of contact time, initial Cr (VI) concentration, and pH.
  • Adsorption data was analyzed using Langmuir and Freundlich isotherms.

Main Results:

  • APLP demonstrated significantly higher adsorption capacity and removal efficiency compared to CPLP.
  • Optimal Cr (VI) removal was achieved at pH 2.
  • The maximum adsorption was observed at a contact time of 165 minutes.
  • Effective adsorption occurred at an initial Cr (VI) concentration of 5 mg/L.
  • Adsorption followed both Langmuir and Freundlich isotherms, with a better fit for the Freundlich model for APLP.

Conclusions:

  • Nitric acid treatment enhances the adsorption performance of pongamia leaf powder for hexavalent chromium removal.
  • Pongamia leaf powder, particularly APLP, shows potential as an eco-friendly and efficient adsorbent for Cr (VI) remediation.
  • The study provides valuable insights into the adsorption mechanism and optimal conditions for chromium removal using biomass-derived adsorbents.