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Size- and solvent-dependent kinetics for cis-trans isomerization in donor-acceptor systems

Hans-Christian Becker1, Kristine Kilså

  • 1Department of Photochemistry and Molecular Sciences, Box 523, Uppsala University, SE-751 20 Uppsala, Sweden.

Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
|February 7, 2009
PubMed
Summary

Investigating charge transfer compounds revealed that cis-trans isomerization dynamics are influenced by molecular size and solvent viscosity. This conformational change breaks conjugation, affecting rotation time after photoexcitation.

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