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Related Concept Videos

Atomic Emission Spectroscopy: Instrumentation01:22

Atomic Emission Spectroscopy: Instrumentation

The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers.  Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.
UV–Vis Spectrometers01:14

UV–Vis Spectrometers

The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell. Samples for...
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy  (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used.
Atomic Absorption Spectroscopy: Instrumentation01:22

Atomic Absorption Spectroscopy: Instrumentation

An atomic absorption spectrophotometer (AAS) comprises several components: a radiation source, an atomizer, a monochromator, and a detector. The radiation source can be a hollow-cathode lamp (HCL) or an electrodeless-discharge lamp (EDL), both of which provide a narrow emission line of the required wavelength. However, some instruments use continuum sources and high-resolution monochromators to achieve a narrow range of radiation.
The atomizer used in AAS can be either a flame atomizer or an...
IR Spectrometers01:25

IR Spectrometers

There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
Raman Spectroscopy Instrumentation: Overview01:26

Raman Spectroscopy Instrumentation: Overview

A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...

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High-speed Continuous-wave Stimulated Brillouin Scattering Spectrometer for Material Analysis
07:55

High-speed Continuous-wave Stimulated Brillouin Scattering Spectrometer for Material Analysis

Published on: September 22, 2017

A single source femtosecond-millisecond broadband spectrometer.

E C Carroll1, M P Hill, D Madsen

  • 1Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California 95616, USA.

The Review of Scientific Instruments
|March 5, 2009
PubMed
Summary

This study introduces a novel spectrometer for time-resolved population dynamics, enabling measurements across 12 decades using a single ultrafast laser system. The technique simplifies complex measurements, as demonstrated with vitamin B(6) dynamics.

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High Speed Sub-GHz Spectrometer for Brillouin Scattering Analysis

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High-speed Continuous-wave Stimulated Brillouin Scattering Spectrometer for Material Analysis
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High Speed Sub-GHz Spectrometer for Brillouin Scattering Analysis

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Area of Science:

  • Physical Chemistry
  • Spectroscopy
  • Laser Physics

Background:

  • Time-resolved measurements of population dynamics over extended timescales (femtosecond to millisecond) typically necessitate complex setups with multiple laser systems.
  • Transient absorption spectroscopy is a key technique for studying ultrafast chemical and physical processes.

Purpose of the Study:

  • To present a novel spectrometer design enabling time-resolved transient absorption measurements over 12 decades of time scales.
  • To demonstrate the utility of this single-laser system for studying population dynamics.

Main Methods:

  • Utilizing a single ultrafast laser system to independently pick pump and probe pulses from the oscillator pulse train.
  • Seeding unamplified pulses into a photonic crystal fiber to generate a supercontinuum probe source for spectrally resolved measurements.
  • Applying the system to measure triplet state dynamics in vitamin B(6) following photoexcitation.

Main Results:

  • Successful implementation of a spectrometer capable of transient absorption measurements spanning 12 orders of magnitude in time.
  • Demonstration of simplified experimental setup by using a single laser system.
  • Acquisition of time-resolved triplet state dynamics data for vitamin B(6).

Conclusions:

  • The presented spectrometer design offers a versatile and simplified approach for broad time-scale population dynamics studies.
  • This method facilitates detailed investigations of excited-state dynamics in various chemical and biological systems.
  • The system's capability is validated through the successful measurement of vitamin B(6) triplet state dynamics.