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Electrochemical Systems01:24

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Electrochemical systems provide a fascinating insight into the dynamic interplay of charged species within various phases. One notable example is the interaction between a membrane permeable to K⁺ ions but not to Cl⁻ ions, separating an aqueous KCl solution from pure water. As K⁺ ions diffuse through the membrane, they generate net charges on each phase, leading to a potential difference between them.Similarly, when a piece of Zn is immersed in an aqueous ZnSO₄ solution, the Zn metal, composed...
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Invasion of a sticky random solid: self-established potential gradient, phase separation, and criticality.

S B Santra1, Santanu Sinha, Jahir Abbas Ahmed

  • 1Department of Physics, Indian Institute of Technology Guwahati, Guwahati-781039, Assam, India.

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|March 5, 2009
PubMed
Summary

This study models sticky solid invasion by aqueous solutions, revealing a self-established potential gradient that drives phase separation and critical, power-law dynamics at the percolation threshold.

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Area of Science:

  • Physical Chemistry
  • Materials Science
  • Chemical Engineering

Background:

  • Modeling the invasion of solids by solutions is crucial for understanding various natural and industrial processes.
  • Understanding the interface dynamics and phase separation during dissolution and redeposition is complex.
  • Previous models often simplify the interaction between the solid and the invading solution.

Purpose of the Study:

  • To model the invasion of a sticky random solid by an aqueous solution using a chemical reaction framework.
  • To investigate the spontaneous formation of a self-established potential gradient (SEPG) and its effect on phase separation.
  • To analyze the system's behavior at the percolation threshold and characterize its nonequilibrium steady state.

Main Methods:

  • Developing a chemical reaction model where solid elements dissolve and redeposit.
  • Introducing a self-established potential gradient (SEPG) to drive the invasion process.
  • Analyzing the system's phase separation into 'hard' and 'soft' solids and its steady-state characteristics.

Main Results:

  • The SEPG drives the solution into the solid at a constant velocity, leading to phase separation.
  • The system spontaneously reaches the percolation threshold, forming invasion percolation clusters.
  • A critical nonequilibrium steady state is observed, characterized by a power-law distribution of cluster sizes (exponent ≈ -2).

Conclusions:

  • The SEPG is a key mechanism governing the invasion dynamics and phase separation in this system.
  • The system's self-tuning to the percolation threshold indicates a critical phenomenon.
  • The observed power-law behavior suggests universal critical dynamics in this type of nonequilibrium process.