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Updated: Mar 7, 2026

Ligand-Mediated Nucleation and Growth of Palladium Metal Nanoparticles
Published on: June 25, 2018
First-order transition in a percolation model with nucleation and preferential growth.
1Department of Physics, Indian Institute of Technology Guwahati, Guwahati-781039, Assam, India.
This study explores a percolation model with preferential growth, revealing how growth parameters and seed concentration influence cluster formation. Compact spanning clusters emerge at low seed concentrations, causing first-order transitions in the system.
Area of Science:
- Complex systems
- Statistical physics
- Network science
Background:
- Percolation theory models random networks and phase transitions.
- Nucleation and preferential growth introduce new dynamics to standard percolation models.
- Understanding cluster formation is crucial in fields like materials science and epidemiology.
Purpose of the Study:
- To investigate the phase transitions in a modified percolation model incorporating nucleation and preferential growth.
- To analyze the impact of the growth parameter (g0) and initial seed concentration (ρ) on spanning cluster properties.
- To characterize the transition from continuous to discontinuous phase transitions.
Main Methods:
- Modification of the standard percolation model to include nucleation and size-dependent preferential growth.
- Systematic variation of the growth parameter (g0) and initial seed concentration (ρ).
- Analysis of spanning cluster formation and transition types (continuous vs. first-order).
Main Results:
- The model exhibits first-order transitions dependent on g0 and ρ.
- A coexistence region of percolative and nonpercolative clusters appears as ρ decreases from the percolation threshold (pc).
- At low ρ (≤0.05) and g0 > pc, compact spanning clusters form, leading to discontinuous, first-order transitions.
Conclusions:
- The modified percolation model demonstrates a rich phase diagram with tunable transition types.
- Preferential growth and nucleation significantly alter cluster formation compared to standard percolation.
- The findings provide insights into the emergence of compact structures and abrupt transitions in complex systems.
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