Mesostructured material based on [Re6Te8(CN)6]4- cluster and Mn(2+): a rational synthesis of hexagonal nonoxidic
Vo Vien1, Min-Jung Suh, Seong Huh
1Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea.
Chemical Communications (Cambridge, England)
|March 14, 2009
Abstract:
A new nonoxidic mesostructured material with highly ordered hexagonal symmetry, [C(16)H(33)N(CH(3))(3)](3)Mn(0.5)[Re(6)Te(8)(CN)(6)], has been obtained through supramolecular assembly of [Re(6)Te(8)(CN)(6)](4-) clusters in the presence of a transition metal cation, Mn(2+), with cetyltrimethylammonium bromide as a liquid crystal template under hydrothermal conditions.
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