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Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
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Trialkylamines more planar at nitrogen than triisopropylamine in the solid state

Minmin Yang1, Thomas Albrecht-Schmitt, Vince Cammarata

  • 1Department of Chemistry and Biochemistry, Auburn University, Auburn, Alabama 36849-5312, USA.

The Journal of Organic Chemistry
|March 28, 2009
PubMed
Summary

Researchers synthesized sterically hindered amines using rhodium carbenoid insertion. These amines exhibit nearly planar nitrogen atoms, challenging previous assumptions about triisopropylamine

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