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Updated: Jun 24, 2026

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Nanoporous polymers for hydrogen storage.

Jonathan Germain1, Jean M J Fréchet, Frantisek Svec

  • 1University of California Berkeley, 94720-1460, USA.

Small (Weinheim an Der Bergstrasse, Germany)
|April 11, 2009
PubMed
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Nanoporous materials, especially porous organic polymers, offer a promising alternative for hydrogen storage. Research focuses on optimizing surface area, pore size, and volume for efficient hydrogen capture and release.

Area of Science:

  • Materials Science
  • Chemical Engineering
  • Energy Storage

Background:

  • Developing a hydrogen economy hinges on effective hydrogen storage materials.
  • Current limitations of metal hydrides include slow kinetics and poor energy efficiency.
  • Nanostructured materials with high surface areas present an alternative to traditional storage methods.

Purpose of the Study:

  • To critically review progress in hydrogen storage using nanoporous materials.
  • To focus specifically on the potential of porous organic polymers for hydrogen storage.
  • To discuss strategies for optimizing hydrogen storage capacity and adsorption enthalpy.

Main Methods:

  • Review of formation mechanisms for various porous organic polymers (crosslinked, hypercrosslinked, polymers of intrinsic microporosity, covalent organic frameworks).

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Last Updated: Jun 24, 2026

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  • Analysis of strategies for controlling material properties like surface area, pore size, and pore volume.
  • Evaluation of how these properties influence hydrogen storage capacity and adsorption enthalpy.

    • Main Results:

    • Porous organic polymers demonstrate potential for overcoming limitations of metal hydrides.
    • Material design strategies allow for tuning of surface area, pore size, and pore volume.
    • These tunable properties directly impact hydrogen storage performance.

    Conclusions:

    • Nanoporous materials, particularly porous organic polymers, are a viable pathway for advanced hydrogen storage.
    • Control over material architecture (surface area, pore size, pore volume) is key to optimizing hydrogen storage.
    • Further research into these materials can accelerate the development of a hydrogen economy.