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UV dosimeter based on dichloroindophenol and tin(IV) oxide.

Andrew Mills1, Pauline Grosshans

  • 1University of Strathclyde, Department of Pure and Applied Chemistry, Thomas Graham Building, 295 Cathedral Street, Glasgow, UKG1 1XL. a.mills@strath.ac.uk

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|April 22, 2009
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Summary

A novel UVB dosimeter uses a redox dye, semiconductor, and electron donor in a polymer film. This indicator changes color with UVB exposure, potentially warning of sunburn risk.

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Area of Science:

  • Photochemistry
  • Materials Science
  • Dermatology

Background:

  • UVB radiation poses risks, necessitating accurate exposure measurement.
  • Current methods for monitoring UVB exposure can be complex or inaccessible.
  • Developing simple, visual indicators for UVB exposure is desirable.

Purpose of the Study:

  • To develop and characterize a novel dosimeter specifically for ultraviolet B (UVB) radiation.
  • To investigate the response of the dosimeter to varying UVB levels and environmental factors.
  • To assess the dosimeter's potential for measuring solar exposure and predicting erythema risk.

Main Methods:

  • A polymer film containing 2,6-dichloroindophenol (DCIP) redox dye, tin(IV) oxide semiconductor, and glycerol electron donor was fabricated.
  • The spectral characteristics and color change mechanism upon UVB exposure were analyzed.
  • The dosimeter's response was correlated with UVB irradiance, exposure duration, and component concentrations.

Main Results:

  • The dosimeter film, initially blue, rapidly decolorizes upon UVB exposure.
  • Response is dependent on UVB irradiance, duration, and tin(IV) oxide concentration.
  • Dosimeter response is independent of dye concentration and film thickness.
  • The color loss correlates with the Minimal Erythemal Dose (MED) for skin type II under simulated solar light.

Conclusions:

  • A simple, visual UVB dosimeter based on DCIP and SnO(2) has been developed.
  • The dosimeter provides a quantifiable response to UVB exposure, related to erythema risk.
  • This technology holds potential for personal solar radiation monitoring and sunburn prevention.