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Related Concept Videos

Spectrophotometry: Introduction01:16

Spectrophotometry: Introduction

Spectrophotometry is the quantitative measurement of the absorption, reflection, diffraction, or transmission of electromagnetic radiation through a material as a function of the intensity and wavelength of the radiation. A spectrophotometer is a device used to measure the change in the radiation intensity caused by its interaction with the material.
The essential components of a spectrophotometer include a source of electromagnetic radiation, a slot for placing a material to be analyzed, and a...
Flame Photometry: Lab01:16

Flame Photometry: Lab

In a flame photometer, when a solution like potassium chloride is aspirated into the flame, the solvent evaporates, leaving behind dehydrated salt. This salt dissociates into free gaseous atoms in their ground state. Some of these atoms absorb energy from the flame, leading to their excitation. The excited atoms return to the ground state, emitting photons at characteristic wavelengths. Because only electronic transitions are involved, the resulting emission lines are very narrow. The intensity...
IR and UV–Vis Spectroscopy of Aldehydes and Ketones01:29

IR and UV–Vis Spectroscopy of Aldehydes and Ketones

Infrared spectroscopy, also known as vibrational spectroscopy, is mainly used to determine the types of bonds and functional groups in molecules. In aldehydes and ketones, the carbonyl (C=O) bond shows an absorption around 1710 cm-1. The C=O bond vibration of an aldehyde occurs at lower frequencies than that of a ketone. In addition to the C=O absorption in an aldehyde, the aldehydic C–H bond also gives two peaks in the 2700–2800 cm-1 range. This absorption, coupled with the C=O stretching, is...
UV–Vis Spectrometers01:14

UV–Vis Spectrometers

The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell. Samples for...
Atomic Absorption Spectroscopy: Lab01:21

Atomic Absorption Spectroscopy: Lab

For AAS measurements, samples must be introduced as clear solutions, often requiring extensive preliminary treatment to dissolve materials like soils, animal tissues, and minerals. Common methods for sample preparation include treatment with hot mineral acids, wet ashing, combustion in closed containers, high-temperature ashing, or fusion with reagents.
 Solutions containing organic solvents, such as low-molecular-mass alcohols, esters, or ketones, enhance absorbances by increasing nebulizer...
Atomic Spectroscopy: Absorption, Emission, and Fluorescence01:23

Atomic Spectroscopy: Absorption, Emission, and Fluorescence

Atomic spectroscopy is a vital tool in elemental analysis, both qualitatively and quantitatively. It can be broadly divided into optical spectroscopy, mass spectroscopy, and X-ray spectroscopy methods. The optical spectroscopic methods are atomic absorption spectroscopy (AAS), atomic emission spectroscopy (AES), and atomic fluorescence spectroscopy (AFS). The first step in all three methods is atomization, where the solid, liquid, or solution-phase samples are converted into gas-phase atoms and...

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Using MazeSuite and Functional Near Infrared Spectroscopy to Study Learning in Spatial Navigation
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[Study of retrieving formaldehyde with differential optical absorption spectroscopy].

Yu-Jin Li1, Pin-Hua Xie, Min Qin

  • 1Key Laboratory of Environment Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China.

Guang Pu Xue Yu Guang Pu Fen Xi = Guang Pu
|April 24, 2009
PubMed
Summary

This study presents a new method for measuring formaldehyde (HCHO) concentration using differential optical absorption spectroscopy (DOAS). The technique accurately quantifies HCHO by simultaneously analyzing SO2, NO2, and O3, achieving high precision.

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Area of Science:

  • Environmental Science
  • Analytical Chemistry
  • Atmospheric Chemistry

Context:

  • Formaldehyde (HCHO) is a key air pollutant with significant environmental and health impacts.
  • Accurate measurement of HCHO is crucial for air quality monitoring and source apportionment.
  • Existing methods for HCHO detection can be affected by interfering gases and spectral complexities.

Purpose:

  • To introduce and validate a novel method for retrieving ambient formaldehyde (HCHO) concentration using differential optical absorption spectroscopy (DOAS).
  • To address challenges in HCHO measurement, including spectral interferences from sulfur dioxide (SO2), nitrogen dioxide (NO2), and ozone (O3), as well as Xenon lamp spectral variations.
  • To develop a robust DOAS-based approach for simultaneous quantification of multiple trace gases.

Summary:

  • The study details the development and application of a custom-built DOAS instrument for measuring ambient HCHO in Beijing.
  • A non-linear least square fitting method was employed for simultaneous retrieval of HCHO, SO2, NO2, and O3 concentrations, mitigating spectral interferences and Xenon lamp structure effects.
  • The method successfully avoids issues related to narrow band selection and residual absorption from interfering species, leading to reliable HCHO concentration data.

Impact:

  • Provides a more accurate and reliable method for monitoring formaldehyde levels in urban atmospheres.
  • Contributes to a better understanding of HCHO sources and atmospheric chemistry.
  • The developed DOAS technique offers a valuable tool for air quality research with a total error within 13.7%.