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Updated: Jun 23, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Scaling analysis of dynamic heterogeneity in a supercooled Lennard-Jones liquid
Richard S L Stein1, Hans C Andersen
1Department of Chemistry, Stanford University, Stanford, California 94305, USA. rstein@ucsd.edu
Abstract:
We have performed molecular dynamics computer simulations of a dense Lennard-Jones liquid mixture to study dynamic heterogeneity from normal liquid temperatures down to a supercooled temperature 15% above the previously identified mode-coupling temperature Tc of the model. A temperature-dependent correlation length associated with the correlation function of mobility fluctuations is calculated. The results are used to test two sets of scaling hypotheses for the dynamic heterogeneity. The results are in close agreement with the inhomogeneous mode-coupling theory of Biroli et al. [Phys. Rev. Lett. 97, 195701 (2006)] for both the alpha and beta relaxation regimes. Comparison with results for kinetically constrained models suggest that the Lennard-Jones mixture studied is more similar to models of fragile liquids than models of very strong liquids.
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