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Free Energy Changes for Nonstandard States

The free energy change for a process taking place with reactants and products present under nonstandard conditions (pressures other than 1 bar; concentrations other than 1 M) is related to the standard free energy change according to this equation:
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An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
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Quantum nonequilibrium steady states induced by repeated interactions.

Dragi Karevski1, Thierry Platini

  • 1Institut Jean Lamour, Département P2M, Groupe de Physique Statistique, Nancy-Université CNRS, B.P. 70239, F-54506 Vandoeuvre les Nancy Cedex, France. karevski@lpm.u-nancy.fr

Physical Review Letters
|June 13, 2009
PubMed
Summary

We investigated the steady state of a finite XX chain interacting with quantum reservoirs. The study reveals an optimal current state dependent on system-reservoir coupling and describes the steady state using a generalized Gibbs state.

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Generation and Coherent Control of Pulsed Quantum Frequency Combs
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Area of Science:

  • Quantum mechanics
  • Statistical mechanics
  • Condensed matter physics

Background:

  • Understanding non-equilibrium quantum systems is crucial.
  • Finite quantum chains coupled to external reservoirs present complex dynamics.

Purpose of the Study:

  • To analyze the steady state of a finite XX chain coupled to quantum reservoirs.
  • To characterize the system's magnetization profile and steady-state current.
  • To explore the influence of system-reservoir coupling on current behavior.

Main Methods:

  • Exact calculation of two-point correlations.
  • Analysis of magnetization profiles and currents.
  • Characterization of the steady state using a generalized Gibbs ensemble.

Main Results:

  • The steady state is defined by magnetization and current.
  • Magnetization equilibrates to the average of reservoir magnetizations (except at boundaries).
  • Steady-state current exhibits nonmonotonic dependence on coupling strength, showing an optimal state.

Conclusions:

  • The steady state of the finite XX chain is fully characterized.
  • A generalized Gibbs state accurately describes the system's non-equilibrium steady state.
  • System-reservoir coupling critically influences transport properties, enabling optimization.