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Updated: Jun 22, 2026

Electric-field Control of Electronic States in WS2 Nanodevices by Electrolyte Gating
Published on: April 12, 2018
Interfacial polarization and field-induced orientation in nanostructured soft-ion conductors
Peter Kohn1, Klaus Schröter, Thomas Thurn-Albrecht
1Institute of Physics, Martin Luther University Halle-Wittenberg, Hoher Weg 8, 06120 Halle, Germany.
Abstract:
We study the effects of interfacial polarization in and upon a self-assembled ion conductor based on a lamellar block copolymer and a lithium salt. Impedance spectroscopy combined with orientation experiments enable a quantitative analysis of ionic polarization and a direct demonstration of its aligning effect on the interfaces. The time constant of the ionic polarization is larger as expected from Maxwell-Wagner-Sillars theory and attributed to diffusion effects. The much stronger orientation effect of ionic vs dielectric polarization offers a new route to align (ion conducting) microdomains.
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