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Related Concept Videos

Ultraviolet and Visible (UV–Vis) Spectroscopy: Overview01:02

Ultraviolet and Visible (UV–Vis) Spectroscopy: Overview

Ultraviolet–visible (UV–visible or UV–Vis) spectroscopy is an analytical technique that investigates the interaction between matter and UV–Vis light within the electromagnetic spectrum. This method is widely used for its versatility, simplicity, and relatively quick data acquisition, making it valuable for both qualitative and quantitative analysis. When UV–Vis radiation passes through a material,  molecules absorb light depending on the energy required for electronic transitions. As a result...
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The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell. Samples for...

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Ultra-sensitive surface absorption spectroscopy using sub-wavelength diameter optical fibers.

F Warken, E Vetsch, D Meschede

    Optics Express
    |June 24, 2009
    PubMed
    Summary

    Sub-wavelength optical fibers detect particle absorption with high sensitivity due to their evanescent fields. This method reveals molecular agglomeration dynamics on surfaces at ambient conditions.

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    Area of Science:

    • Optics and Photonics
    • Materials Science
    • Chemical Sensing

    Background:

    • Sub-wavelength optical fibers possess strong evanescent fields.
    • Evanescent fields interact with particles on the fiber surface.
    • Conventional surface spectroscopy has limitations in sensitivity.

    Purpose of the Study:

    • To demonstrate a novel method for detecting particle absorption on optical fibers.
    • To leverage evanescent fields for enhanced surface spectroscopy.
    • To study molecular agglomeration dynamics.

    Main Methods:

    • Utilizing sub-wavelength diameter air-clad optical fibers.
    • Measuring fiber transmission to detect surface absorption.
    • Employing 3,4,9,10-perylene-tetracarboxylic dianhydride (PTCDA) as a model molecule.

    Main Results:

    • Absorption detection via fiber transmission is orders of magnitude higher than conventional methods.
    • Sensitive detection of sub-monolayers of PTCDA molecules was achieved.
    • Real-time observation of PTCDA agglomeration dynamics over seconds to minutes.

    Conclusions:

    • Sub-wavelength optical fibers offer a highly sensitive platform for surface spectroscopy.
    • The evanescent field effect significantly enhances particle absorption detection.
    • This technique is suitable for studying dynamic processes like molecular agglomeration at ambient conditions.