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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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Electrochemical reactions at a porphyrin-copper interface

Nguyen T M Hai1, Shuhei Furukawa, Tom Vosch

  • 1Institute for Physical and Theoretical Chemistry, University of Bonn, Wegeler Str. 12, D-53115 Bonn, Germany.

Physical Chemistry Chemical Physics : PCCP
|June 25, 2009
PubMed
Summary

A stable porphyrin layer on copper prevents copper dissolution by forming a new copper-porphyrin complex. This complex accumulates in solution, inhibiting copper redeposition during electrochemical cycling.

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