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Updated: Jun 22, 2026

Measurement of the Potential Rates of Dissimilatory Nitrate Reduction to Ammonium Based on 14NH4+/15NH4+ Analyses via Sequential Conversion to N2O
Published on: October 7, 2020
[Half-nitrosofication of dewatering liquid of digested sludge with high ammonia]
Shu-Jun Zhang1, Fan-Neng Meng, Jian Lü
1Key Laboratory of Beijing for Water Quality Science and Water Environmental Recovery Engineering, Beijing University of Technology, Beijing 100022, China. lxzsj@tom.com
Achieving stable half-nitrosation in digested sludge dewatering liquid requires maintaining high free ammonia (FA) levels above 4 mg/L in A/O reactors. This process enhances total nitrogen removal by conserving carbon sources.
Area of Science:
- Environmental Engineering
- Microbiology
- Wastewater Treatment
Context:
- Digested sludge dewatering liquid presents challenges for nitrogen removal.
- Achieving partial nitrification (half-nitrosation) is crucial for efficient wastewater treatment.
- A/O (Anaerobic/Oxic) processes are commonly used in wastewater treatment.
Purpose:
- To investigate the factors affecting and methods for achieving and maintaining half-nitrosation of digested sludge dewatering liquid.
- To identify optimal operational conditions for stable partial nitrification.
- To understand the role of free ammonia (FA) in maintaining half-nitrosation.
Summary:
- Half-nitrosation was achieved in 29 days under specific conditions (9-20°C, 5.4 mg/L DO, 30 d SRT, 0.64 kg/(m³·d) ammonia loading).
- Stable nitritation with 70% nitrite accumulation was maintained for 65 days when FA > 4 mg/L.
- Half-nitrosation was confirmed with an effluent ammonia to nitrite ratio of 1:1.32, and high FA was proven critical for its maintenance.
Impact:
- Demonstrates that maintaining FA > 4 mg/L in A/O reactors enables stable half-nitrosation.
- Highlights the potential for enhanced total nitrogen removal (91 mg/L) due to carbon source conservation.
- Provides a method for controlling half-nitrosation through dynamic adjustment of ammonia loading and pH at moderate/low temperatures.
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