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A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis

Zhuojia Lin1, David S Wragg, Philip Lightfoot

  • 1EaStChem School of Chemistry, University of St. Andrews, St Andrews, Fife, Scotland, UKKY16 9ST.

Dalton Transactions (Cambridge, England : 2003)
|July 1, 2009
PubMed

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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.