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Updated: Jun 22, 2026

Atomic Scale Structural Studies of Macromolecular Assemblies by Solid-state Nuclear Magnetic Resonance Spectroscopy
Published on: September 17, 2017
Complete (1)H and (13)C signal assignment of prenol-10 with 3D NMR spectroscopy
Maria Misiak1, Wiktor Koźmiński, Maria Kwasiborska
1Chemistry Department, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland.
Abstract:
The complete assignment of (1)H and (13)C chemical shifts of natural abundance prenol-10 is reported for the first time. It was achieved using 3D NMR experiments, which were based on random sampling of the evolution time space followed by multidimensional Fourier transform. This approach makes it possible to acquire 3D NMR spectra in a reasonable time and preserves high resolution in indirectly detected dimensions. It is shown that the interpretation of 3D COSY-HMBC and 3D TOCSY-HSQC spectra is crucial in the structural analysis of prenol-10.
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