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Solvothermal reduction of chemically exfoliated graphene sheets

Hailiang Wang1, Joshua Tucker Robinson, Xiaolin Li

  • 1Department of Chemistry and Laboratory for Advanced Materials, Stanford University, Stanford, California 94305, USA.

Journal of the American Chemical Society
|July 8, 2009
PubMed

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Reduction is a simple strategy to convert a carbonyl group to a hydroxyl group. The three major pathways to reduce carbonyls to alcohols are catalytic hydrogenation, hydride reduction, and borane reduction.
Catalytic hydrogenation is similar to the reduction of an alkene or alkyne by adding H2 across the pi bond in the presence of transition metal catalysts like Raney Ni, Pd–C, Pt, or Ru. Aldehydes and ketones can be reduced by this method, often under mild to moderate heat (25–100°C) and...