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Updated: Jun 21, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Prototypes of molecular motors based on star-shaped organometallic ruthenium complexes
Guillaume Vives1, Henri-Pierre Jacquot de Rouville, Alexandre Carella
1CNRS, CEMES (Centre d'Elaboration des Matériaux et d'Etudes Structurales), BP 94347, 29 rue J. Marvig, F-31055 Toulouse, France.
Abstract:
This tutorial review presents our strategy to control the rotation in a molecular rotary motor, and the family of star-shaped ruthenium complexes designed to perform such a task. The molecules have a piano-stool structure with a "stator" meant to be grafted on a surface, and a "rotor" bearing redox-active groups, so that addressing the molecule with nano-electrodes would trigger rotation.
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