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Updated: Jun 21, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
Published on: December 16, 2022
Synthetic approaches for the preparation of cyclic polymers
Boyd A Laurent1, Scott M Grayson
1Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Abstract:
Despite decades of studies devoted to the unique physical properties and potential applications of cyclic polymer topologies, their exploration has remained limited because of synthetic inefficiencies and acyclic impurities. Many recently developed synthetic techniques offer efficient routes to well-defined cyclic macromolecules to answer this need. This tutorial review aims to provide a concise overview of the most significant synthetic contributions in this field, and highlight the relative advantages and disadvantages of each approach.
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