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Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems
Published on: April 28, 2016
Thermal stability of strained nanowires
Cristiano Nisoli1, Douglas Abraham, Turab Lookman
1Theoretical Division and Center for Nonlinear Studies, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.
Physical Review Letters
|August 8, 2009
Summary
Thermal fluctuations can cause strained nanowires to transform back into nanoislands, revealing new phase transitions and coexistence regions in nanostructure stability.
Area of Science:
- Materials Science
- Surface Science
- Thermodynamics
Background:
- Stranski-Krastanow islands exhibit shape anisotropy, transitioning to nanowires with growth.
- Existing models for this transition overlook thermodynamic effects.
Purpose of the Study:
- Investigate the thermodynamic stability of strained nanowires.
- Analyze the impact of thermal fluctuations on nanowire shape.
- Identify phase transitions and coexistence phenomena.
Main Methods:
- Theoretical investigation of strained nanowire stability.
- Modeling thermal fluctuations on nanostructure dimensions.
- Analysis of phase transitions under varying temperature and height.
Main Results:
- Discovered phase transitions from nanowires back to nanoislands with increasing temperature.
- Observed transitions occur with changes in nanostructure height (increase or decrease).
- Predicted regions of phase coexistence between nanowire and nanoisland structures.
Conclusions:
- Thermodynamics and thermal fluctuations are crucial for understanding nanostructure shape evolution.
- The findings explain recent experimental data on erbium silicide growth on silicon surfaces.
- Highlights the dynamic nature of nanostructure morphology beyond simple energetic considerations.
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Thermal expansion and Thermal stress: Problem Solving
San Francisco's Golden Gate Bridge is exposed to temperatures ranging from -15 °C to 40 °C. At its coldest, the main span of the bridge is 1275 m long. Assuming that the bridge is made entirely of steel, what is the change in its length between these temperatures?
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in temperature (ΔT) is 55 °C.
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in temperature (ΔT) is 55 °C.
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