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Cobaltabisdicarbollide anion receptor for enantiomer-selective membrane electrodes

Anca-Iulia Stoica1, Clara Viñas, Francesc Teixidor

  • 1Institut de Ciència de Materials de Barcelona CSIC Campus de la U.A.B., 08193 Bellaterra, Spain.

Chemical Communications (Cambridge, England)
|August 12, 2009
PubMed

Abstract:

A potentiometric sensor for enantiomers has been prepared with no chiral additives, only cobaltabisdicarbollide and the protonated enantiomer.

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Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at the...

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