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Updated: Jun 20, 2026

In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework
Published on: February 1, 2020
Infrared hole-burning spectroscopy of matrix-isolated ReO(4)(-)molecules
Abstract:
CO(2)-laser-diode-laser hole-burning spectroscopy has been used to measure the temperature-dependent homogeneous linewidth of the ReO(4)(-) infrared active internal-vibrational mode (nu(3)) in alkali halide lattices. Hole widths as small as 20 MHz (FWHM) have been observed in an inhomogeneously broadened line of width as large as 1 cm(-1). Our measurement of the homogeneous linewidth over 4 orders of magnitude indicates that elastic acoustic phonon scattering is the dominant T(2) relaxation process from 10 to 600 K.
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