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Related Concept Videos

NMR Spectrometers: Resolution and Error Correction01:14

NMR Spectrometers: Resolution and Error Correction

When magnetic nuclei in a sample achieve resonance and undergo relaxation, the signal detected in NMR is an approximately exponential free induction decay. Fourier transform of an exponential decay yields a Lorentzian peak in the frequency domain. Lorentzian peaks in an NMR spectrum are defined by their amplitude, full width at half maximum, and position, where the peak width is governed by the spin-spin relaxation time alone. In real experiments, however, the applied magnetic field is rendered...
UV–Vis Spectroscopy: Molecular Electronic Transitions01:16

UV–Vis Spectroscopy: Molecular Electronic Transitions

In Ultraviolet–Visible (UV–Vis) spectroscopy, the absorption of electromagnetic radiation is used to probe the electronic structure of molecules. This technique provides insights into molecular electronic transitions, particularly the movement of electrons between different molecular orbitals. Radiation is absorbed if the energy of the electromagnetic radiation passing through the molecule is precisely equal to the energy difference between the excited and ground states. During this process,...
¹³C NMR: ¹H–¹³C Decoupling01:04

¹³C NMR: ¹H–¹³C Decoupling

The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...

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Related Experiment Video

Updated: Jun 20, 2026

Construction and Characterization of External Cavity Diode Lasers for Atomic Physics
09:10

Construction and Characterization of External Cavity Diode Lasers for Atomic Physics

Published on: April 24, 2014

Spectroscopic decay-rate measurements below the laser linewidth.

W E Cooke, S A Bhatti, C L Cromer

    Optics Letters
    |August 28, 2009
    PubMed
    Summary

    This study introduces a laser-based method to measure atomic decay rates, even when they are very small. The technique uses depletion broadening to accurately determine autoionizing rates of specific atomic states.

    Area of Science:

    • Atomic Physics
    • Quantum Optics
    • Laser Spectroscopy

    Background:

    • Measuring decay rates of excited atomic states is crucial for understanding atomic structure and dynamics.
    • Traditional methods can be limited by factors like inhomogeneous broadening and laser linewidths, especially for small decay rates.

    Purpose of the Study:

    • To develop and apply a novel laser-based technique for measuring atomic decay rates.
    • To accurately determine autoionizing rates for specific 6P((1/2))ns states.

    Main Methods:

    • Utilizing strong coupling between two atomic levels with a pulsed laser.
    • Employing depletion broadening, where transition broadening is proportional to the square root of decay rate and laser pulse energy density.
    • Applying high laser power to overcome limitations of inhomogeneous broadening and laser linewidth.

    More Related Videos

    Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown
    09:40

    Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown

    Published on: February 14, 2014

    Related Experiment Videos

    Last Updated: Jun 20, 2026

    Construction and Characterization of External Cavity Diode Lasers for Atomic Physics
    09:10

    Construction and Characterization of External Cavity Diode Lasers for Atomic Physics

    Published on: April 24, 2014

    Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown
    09:40

    Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown

    Published on: February 14, 2014

    Main Results:

    • Demonstrated a method to measure decay rates significantly smaller than other broadening factors.
    • Successfully measured autoionizing rates of selected 6P((1/2))ns states using the depletion broadening technique.

    Conclusions:

    • The depletion broadening technique provides a powerful tool for measuring atomic decay rates, particularly for weak transitions.
    • This method offers enhanced sensitivity and accuracy in atomic spectroscopy, enabling the study of previously challenging states.