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Synthesis of 1-methyleneindenes via palladium-catalyzed tandem reactions
Shengqing Ye1, Ke Gao, Haibo Zhou
1Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China.
Chemical Communications (Cambridge, England)
|September 3, 2009
Abstract:
Palladium-catalyzed tandem reactions of 2-alkenylphenyl-acetylenes with CuCl2 or CuBr2 afforded 3-chloro- or 3-bromo-1-methyleneindenes in good yields; these compounds could be further elaborated via palladium-catalyzed coupling reactions.
