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Synthesis and characterization of heterometallic {Cr7M} wheels

Finn K Larsen1, Eric J L McInnes, Hassane El Mkami

  • 1Department of Chemistry, University of Aarhus, 8000 Arhus C, Denmark.

Angewandte Chemie (International Ed. in English)
|September 18, 2009
PubMed
Abstract

No abstract available in PubMed .

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Properties of Organometallic Compounds

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The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.
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Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...

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