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Published on: August 19, 2013
Acridinium salt-based fluoride and acetate chromofluorescent probes: molecular insights into anion selectivity
1Department of Chemistry, National Taiwan University, Taipei, Taiwan 106, ROC.
Organic Letters
|October 6, 2009
Abstract:
A series of acridinium salt-based probes capable of detecting fluoride and acetate anions via a nucleophilic attack at the C9 position of the acridinium moiety is reported. The formation of corresponding acridane displays drastic changes, in both UV-vis absorption and fluorescence emission. The sensing mechanism is a reversible process upon treating either tetrafluoroborate salt or an acid.

