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Updated: Jun 19, 2026

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
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Published on: February 10, 2023

MOF@MOF: microporous core-shell architectures.

Kyoungmoo Koh1, Antek G Wong-Foy, Adam J Matzger

  • 1Department of Chemistry, Macromolecular Science and Engineering, University of Michigan, Ann Arbor, MI 48109-1055, USA.

Chemical Communications (Cambridge, England)
|October 15, 2009
PubMed
Summary
This summary is machine-generated.

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Researchers created metal-organic frameworks (MOFs) using two linkers. This method allows for control over the composition of the resulting coordination copolymers, creating either random or core-shell structures.

Area of Science:

  • Materials Science
  • Chemistry
  • Nanotechnology

Background:

  • Metal-organic frameworks (MOFs) are crystalline materials constructed from metal ions or clusters and organic linkers.
  • MOFs offer tunable properties making them suitable for various applications.
  • Controlling the composition and structure of MOFs is crucial for optimizing their performance.

Purpose of the Study:

  • To investigate the synthesis of metal-organic frameworks (MOFs) using a mixture of two different linkers.
  • To explore methods for generating coordination copolymers with controlled linker arrangements.
  • To achieve either randomly mixed or core-shell compositions within the MOF structure.

Main Methods:

  • Employing a one-batch or sequential mixing strategy for two distinct linkers with identical topology.

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  • Utilizing established synthetic protocols for metal-organic framework (MOF) construction.
  • Characterizing the resulting coordination copolymers to determine linker distribution and morphology.

    • Main Results:

    • Successfully synthesized metal-organic frameworks (MOFs) by combining two different linkers.
    • Demonstrated the ability to control the linker composition, achieving both random and core-shell architectures.
    • The chosen synthetic approach (one-batch vs. sequential) dictates the final linker arrangement.

    Conclusions:

    • Mixing linkers with the same topology is an effective strategy for creating diverse MOF structures.
    • The synthesis method allows for precise control over coordination copolymer composition.
    • This work provides a pathway for designing MOFs with tailored properties for specific applications.