Fluorescent protein red Kaede chromophore; one-step, high-yield synthesis and potential application for solar cells
Wei-Ti Chuang1, Bo-So Chen, Kew-Yu Chen
1Department of Chemistry, National Taiwan University, Taipei 106, Taiwan.
Abstract:
The one-step condensation between the Green Fluorescence Protein (GFP) chromophore and 1H-imidazole-5-carbaldehyde catalyzed by ZnCl(2) proved to be a facile method to synthesize the red Kaede chromophore and its derivatives (1a-d, 2, and 3 > 70%), among which 1a then demonstrated its potential as a dye in solar cell, with a moderate conversion efficiency (eta) of 3.04%.
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