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Related Concept Videos

Atomic Nuclei: Nuclear Relaxation Processes01:23

Atomic Nuclei: Nuclear Relaxation Processes

In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis,  the precessing magnetic moments are randomly oriented around the z-axis. This...
Atomic Nuclei: Types of Nuclear Relaxation01:28

Atomic Nuclei: Types of Nuclear Relaxation

Nuclear relaxation restores the equilibrium population imbalance and can occur via spin–lattice or spin–spin mechanisms, which are first-order exponential decay processes.
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers energy to a nearby...
Spin–Spin Coupling Constant: Overview01:08

Spin–Spin Coupling Constant: Overview

In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must have a...
Spin–Spin Coupling: One-Bond Coupling01:17

Spin–Spin Coupling: One-Bond Coupling

Coupling interactions are strongest between NMR-active nuclei bonded to each other, where spin information can be transmitted directly through the pair of bonding electrons. While nuclei polarize their electrons to the opposite spins, the bonding electron pair has opposite spins. Configurations with antiparallel nuclear spins are expected to be lower in energy. When coupling makes antiparallel states more favorable, J is considered to have a positive value. The one-bond coupling constant, 1J,...
Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)

Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...

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Related Experiment Video

Updated: Jun 18, 2026

Experimental Methods for Spin- and Angle-Resolved Photoemission Spectroscopy Combined with Polarization-Variable Laser
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Experimental Methods for Spin- and Angle-Resolved Photoemission Spectroscopy Combined with Polarization-Variable Laser

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Spin-orbit-mediated spin relaxation in graphene.

D Huertas-Hernando1, F Guinea, Arne Brataas

  • 1Department of Physics, Norwegian University of Science and Technology, NO-7491, Trondheim, Norway.

Physical Review Letters
|November 13, 2009
PubMed
Summary

In intrinsic graphene, spin relaxation is dominated by the Dyakonov-Perel mechanism and gauge fields. Spin-flip relaxation time inversely correlates with elastic scattering time.

Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Spintronics

Background:

  • Understanding spin relaxation mechanisms in 2D materials like graphene is crucial for spintronic applications.
  • Intrinsic graphene possesses unique electronic properties influenced by its band structure and potential imperfections.
  • Spin-orbit coupling and ripple-induced effects are key factors affecting electron spin dynamics.

Purpose of the Study:

  • To investigate the dominant spin relaxation mechanisms in intrinsic graphene.
  • To analyze the influence of spin-orbit coupling, scattering centers, and ripple-induced gauge fields on spin dynamics.
  • To determine the relationship between spin-flip relaxation time and elastic scattering time.

Main Methods:

  • Theoretical analysis of spin relaxation processes, including Elliot-Yafet and Dyakonov-Perel mechanisms.

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  • Modeling the effects of ripple-induced gauge fields in combination with spin-orbit coupling.
  • Investigating the role of scattering centers on orbital motion.
  • Main Results:

    • The Dyakonov-Perel mechanism and spin flip due to gauge fields are identified as dominant in intrinsic graphene.
    • The spin-flip relaxation time is found to be inversely proportional to the elastic scattering time.
    • Spin-relaxation anisotropy arises from a complex interplay between these relaxation mechanisms.

    Conclusions:

    • Intrinsic graphene exhibits dominant spin relaxation via the Dyakonov-Perel mechanism and gauge field effects.
    • The elastic scattering time critically influences the spin relaxation rate.
    • The findings provide insights into controlling spin lifetimes for potential spintronic devices.