Element-specific magnetometry of EuS nanocrystals

A soft x-ray absorption and x-ray magnetic circular dichroism (XMCD) study of the ferromagnetism in solution-grown EuS nanocrystals (NCs) is reported. The absorption edges of Eu M(5) and M(4), S K, O K, and P K were probed to determine elementally specific contributions to the magnetism of EuS NCs. Differential spin absorption was observed by XMCD at the Eu M(5,4) edges confirming the presence of a magnetic moment on the Eu(2+) 4f shell. No dichroic signal was observed for S, O, or P. Vibrating sample magnetometry of ensembles of NCs shows ferromagnetic properties consistent with the XMCD studies.